Arsenide chloride

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Arsenide chlorides or chloride arsenides are compounds containing anions composed of chloride (Cl−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide bromides, arsenide iodides, phosphide chlorides, and antimonide chlorides.

List[edit]

formula system space group unit cell Å volume density comment ref
Ca3AsCl3 Pm3m a= 5.760 [1]
Sr2AsCl dark violet [2]
Cd8As7Cl cubic P23 a=7.266, Z=1 [3]
Hg7.4As4Cl6 cubic Pa3 a= 12.178, Z= 4 [4]
(Hg6As4)(HgCl6)Hg0.5 cubic Pa3 a=12.189 Z=4 1810.7 7.398 yellow; air stable; band gap 2.01 [5]
(Hg6As4)[TiCl6]Cl cubic Pa3 a = 1209.4 [6]
[Hg4As2][ZrCl6] orthorhombic Pbca a=13.277 b=13.420 c=16.814 Z=8 2769.1 5.570 dark yellow [7]
[Hg4As2][HfCl6] orthorhombic Pbca a=13.273 b=13.413 c=16.809 Z=8 2992 5.964 orange [7]
(Hg3AsS)(GaCl4) hexagonal P63/mc a =7.245, c =11.960 , Z = 2 543.6 5.622 light yellow [8]
Hg3AsS4Cl hexagonal P63mc a = 7.431, c = 9.003 Z=2 yellow; air stable [9]
[Hg6As4](CuCl3)2 monoclinic I2/a a = 14.690, b = 9.1851, c = 20.285, β=92.170, Z=6 [10]
(Hg9.75As5.5)(GaCl4)3 orthorhombic Pmn21 a=22.567 b=12.146 c=12.983 Z=4 3559 5.604 [11]
(Hg6As4)[MoCl6]Cl cubic Pa3 a = 12.078 [6]
[Hg6As4](AgCl3)2 monoclinic I2/a a = 14.690, b = 9.1851, c = 20.285, β = 93.17°, Z = 4 [10][12]
(Hg6As4)(CdCl6)Hg0.5 cubic Pa3 a=12.172 Z=4 1803.2 7.104 yellow; air stable; band gap 2.05 [5]
[Hg6As4](InCl6)Cl cubic Pa3 a = 12.109, Z = 4 dark red [13]
[Hg6As4Cl3](SnCl3)Hg0.13 cubic P213 a=12.233 Z=4 [14]
Hg3As2TlCl3 orthorhombic Pbcm a = 6.292, b = 12.341 c = 12.248 Z=4 red [15]
Hg6As4BiCl7 cubic Pa3 a=12.178 Z=4 [16]
[Hg4As2][UCl6] orthorhombic Pbca a=13.316 b=13.636 c=16.853 Z=8 3060.0 6.090 red [7][17]

References[edit]

  1. ^ Hadenfeldt, C.; Vollert, H. O. (August 1982). "Darstellung, thermisches Verhalten und Kristallstruktur des Calciumarsenidchlorids Ca3AsCl3". Zeitschrift für anorganische und allgemeine Chemie (in German). 491 (1): 113–118. doi:10.1002/zaac.19824910115. ISSN 0044-2313.
  2. ^ Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3". Zeitschrift für Naturforschung B. 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. S2CID 95122668.
  3. ^ Shevelkov, Andrei V.; Reshetova, Ludmila N.; Popovkin, Boris A. (December 1997). "Cd8As7Cl: A Novel Pnictidohalide with a New Structure Type". Journal of Solid State Chemistry. 134 (2): 282–285. Bibcode:1997JSSCh.134..282S. doi:10.1006/jssc.1997.7555.
  4. ^ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996). "Two New Cubic Structures of Mercury Arsenidehalides". Journal of Solid State Chemistry. 126 (2): 324–327. Bibcode:1996JSSCh.126..324S. doi:10.1006/jssc.1996.0344.
  5. ^ a b Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948.
  6. ^ a b Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie. 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
  7. ^ a b c Li, Xiao-Guo; Jiang, Xiao-Ming; Zhang, Ming-Jian; Liu, Bin-Wen; Fan, Yu-Hang; Guo, Guo-Cong; Huang, Jin-Shun (2013-12-02). "Three-Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)". European Journal of Inorganic Chemistry. 2013 (35): 5980–5986. doi:10.1002/ejic.201300888. ISSN 1434-1948.
  8. ^ Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013). "New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)". Dalton Transactions. 42 (43): 15475–15481. doi:10.1039/c3dt51451j. ISSN 1477-9226. PMID 24022795.
  9. ^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
  10. ^ a b Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework". Journal of Cluster Science. 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. S2CID 95453360.
  11. ^ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014). "Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions". Chemistry: An Asian Journal. 9 (10): 2872–2879. doi:10.1002/asia.201402572. PMID 25110860.
  12. ^ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (October 2004). "From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3 ) 2 Assembly Featuring One-Dimensional (AgCl 3 ) 2− Anions". European Journal of Inorganic Chemistry. 2004 (20): 4006–4010. doi:10.1002/ejic.200400205. ISSN 1434-1948.
  13. ^ Olenev, A. V.; Baranov, A. I.; Shatruk, M. M.; Tyablikov, A. S.; Shevelkov, A. V. (2002). "Synthesis and the crystal structure of [Hg6As4](InCl6)Cl: influence of covalent and electrostatic factors on the supramolecular structure". Russian Chemical Bulletin. 51 (3): 444–448. doi:10.1023/A:1015500116907. S2CID 92070325.
  14. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
  15. ^ Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg3As2TlCl3 und Hg3Sb2TlBr3". Zeitschrift für Anorganische und Allgemeine Chemie. 627 (8): 2016–2022. doi:10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N.
  16. ^ Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000). "Synthesis and Crystal Structures of Hg6Sb5Br7, Hg6As4BiCl7, and Hg6Sb4BiBr7, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions". Journal of Solid State Chemistry. 154 (2): 350–355. Bibcode:2000JSSCh.154..350B. doi:10.1006/jssc.2000.8794.
  17. ^ Bugaris, Daniel E.; Ibers, James A. (December 2008). "Syntheses, structures, and magnetic and optical properties of the compounds [Hg3Te2][UCl6] and [Hg4As2][UCl6]". Journal of Solid State Chemistry. 181 (12): 3189–3193. Bibcode:2008JSSCh.181.3189B. doi:10.1016/j.jssc.2008.08.019.
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