Pendant group

IUPAC definition for pendant group (side group) in polymer chemistry

In IUPAC nomenclature of chemistry, a pendant group (sometimes spelled pendent) or side group is a group of atoms attached to a backbone chain of a long molecule, usually a polymer. Pendant groups are different from pendant chains, as they are neither oligomeric nor polymeric.

For example, the phenyl groups are the pendant groups on a polystyrene chain.

Large, bulky pendant groups such as adamantyl usually raise the glass transition temperature (T_g) of a polymer by preventing the chains from sliding past each other easily. Short alkyl pendant groups may lower the T_g by a lubricant effect.